HYDROGEN is the simplest and most
abundant of elements. Composed of one proton and one electron, it makes
up 90% of our universe (by number of atoms). On Earth, hydrogen is commonly
found as a diatomic molecular gas. But on Jupiter, where interior pressure
is millions of times greater than that at our planet's surface, the hydrogen
molecule is theorized to exist as a superhot liquid metal. The theory that hydrogen turns
metallic under extreme pressure was first advanced in 1935 by Eugene Wigner,
who would go on to win a 1963 Nobel Prize in physics for his work in quantum
mechanics. Finding experimental evidence of Wigner's hydrogen metallization
theory, however, has proven to be extremely difficult for the scientific
community. While studies of the universe's lightest material led to discovery
of hydrogen's solid and liquid phases, metallic hydrogen remained out of
reach--until recently.1 At Lawrence Livermore National
Laboratory, in a series of shock compression experiments funded by Laboratory
Directed Research and Development grants, we successfully ended a 60-year
search for hard evidence of metallic hydrogen and the precise pressure at
which metallization occurs at a particular temperature. Our success in metallizing hydrogen
would not have been achieved without the shock-wave technology built up
over more than two decades to support Lawrence Livermore's nuclear weapons
program. It represents the integration of the Laboratory's broad capabilities
and expertise in gas-gun technology, shock physics, target diagnostics,
hydrodynamic computational simulations, cryogenics, and hydrogen and condensed-matter
physics. Knowing what happens when matter,
such as hydrogen, encounters enormously high pressure and temperature is
critical for the success of the Laboratory's research in areas relevant
to our science-based stockpile stewardship mission, such as nuclear explosives,
conventional high explosives, and laser fusion, as well as for our collaborative
efforts in planetary science research. For more than two decades, we have
been helping improve that understanding through shock-compression studies
using our two-stage light-gas gun (see the box below).
|
How Our Gas Gun Works
Our shock compression studies use a 20-meter-long, two-stage light-gas gun built by General Motors in the mid-1960s for ballistic missile studies; the gun has been in operation at the Laboratory since 1972.
The gun consists of a first-stage breech containing up to 3.5 kilograms of gunpowder and a pump tube filled with 60 grams of hydrogen, helium, or nitrogen gas; and a second-stage evacuated barrel for guiding the high-velocity impactor to its target.
Hot gases from the burning gunpowder drive a heavy (4.5- to 6.8-kilograms) piston down the pump tube, compressing the gas. At sufficiently high pressures, the gas eventually breaks a rupture valve and enters the narrow barrel, propelling a 20-gram impactor housed in the barrel toward the target.
When the impactor hits the target, it produces a high-pressure shock wave. In a fraction of a microsecond, the shock wave reverberates through the target. Diagnostic equipment, triGasGunered by the initial wave, measures the properties of the shocked material inside the target during this extremely brief period.
Projectile velocity can range from 1 to 8 kilometers per second (up to 18,000 mph). The preferred velocity is achieved by selecting the appropriate type and amount of gunpowder, driving gas (hydrogen for velocities at or above 4 kilometers per second, helium and nitrogen for lower velocities), pressure required to open the rupture valve, diameter of the barrel, and the metal and mass of the impactor.
The velocity of the shock wave, when combined with the initial conditions (impactor velocity, known densities, equation of state of the projectile and target materials) yields a precise measure of the pressure, density, and energy attained.
The gas gun permits
us to fire hypervelocity projectiles into highly instrumented targets (Figure
1), shocking matter to extreme conditions for a millionth of a second or
less. These experiments create pressures of a million-plus atmospheres,
temperatures up to thousands of degrees depending upon the material being
shocked, and densities several times that of a material's solid state. In addition to hydrogen, we have
performed shock compression experiments on other liquefied gases such as
nitrogen, water, carbon dioxide, oxygen, carbon monoxide, deuterium (an
isotope of hydrogen), helium, and argon, and on solids such as aluminum,
copper, tantalum, and carbon (graphite). Data from such experiments are
used to determine a material's equation of state (EOS expresses the relationship
between pressure, density, and temperature), to validate theories, and to
generate reliable computational models of a material's behavior under a
wide range of thermodynamic variables.
|

Quest for Metallic Hydrogen Under normal conditions on our
planet, molecular hydrogen functions as an insulator, blocking electrical
flow. Apply sufficient pressure, theory said, and hydrogen turns metallic,
becoming an exceptional conductor of electricity. Theory predicted that
metallization would occur when the insulating molecular solid would transform
to a metallic monatomic solid at absolute zero--0 degrees kelvin (K) or
-460°F. For early metallic hydrogen theorists, "sufficient pressure"
was thought to be 0.2 megabars (1 bar is atmospheric pressure at sea level;
a megabar, or Mbar, is a million times atmospheric pressure at sea level).
Subsequent predictions pushed metallization pressure to as high as 20 Mbar.
At the time our experiments were conducted, the prevailing theory predicted
3 Mbar for solid hydrogen at 0 K. For 35 years after Wigner proposed
his theory, studies on metallic hydrogen were relegated to the theoretical
realm because there was no way to approach the subject experimentally. By
the 1970s, however, the tools of science had reached a point where it became
possible to construct experiments aimed at creating conditions that theory
said were required for metallization. At Lawrence Livermore, for example,
one research approach2 used an explosively driven system that
compressed a magnetic field and, in turn, a small sample of hydrogen to
megabar pressures without shocking the hydrogen, and thus the temperature
of the sample was kept very low. The early Livermore experiments generated
pressures similar to those we recently reached (about 2 Mbar). While electrical
conductivity was measured, the approach did not provide necessary evidence
of metallization; the measurement system was only sensitive to conductivity
values much less than that of a metal. In recent years, researchers at
other laboratories have attempted to achieve metallization by crushing micrometer-sized
samples of crystalline hydrogen in a diamond anvil cell. This small mechanical
press creates very high pressures in a nanogram-sized sample when the small
flat faces of two flawless diamonds are forced together, exerting megabar
pressure on the sample trapped between them.3 While diamond anvil
studies of hydrogen resulted in an initial claim of optical evidence for
metallization, this claim was later found to not hold up.4 Significantly,
there was no establishment of metallic character using optical probes. Metallic
character is most directly established by electrical conductivity measurements,
which are not yet possible in diamond anvil cells with hydrogen samples
at any pressure.
Our Approach |
Our Results As shown in Figure 2, we found
that from 0.9 to 1.4 Mbar, resistivity in the shocked fluid decreases almost
four orders of magnitude (i.e., conductivity increases); from 1.4 to 1.8
Mbar, resistivity is essentially constant at a value typical of that of
liquid metals. Our data indicate a continuous transition from a semiconducting
to metallic diatomic fluid at 1.4 Mbar, nine-fold compression of initial
liquid density, and 3,000 K. Some theorists have speculated
that metallic hydrogen produced under laboratory conditions might remain
in that state after the enormous pressures required to create it are removed.
However, metallization in our experiments occurred for such a brief period
of time, and in such a manner, that questions about hydrogen's superconducting
properties and retention of metallic form could not be answered. At the relatively low temperature,
the fluid hydrogen remained almost essentially molecular, rather than breaking
into individual atoms. As a result, electrons in the sample freely flowed
from molecule to molecule in a fashion that is characteristic of metals.
At metallization, we calculate that only about 5% of the original molecules
have separated into individual atoms of hydrogen, which means that our metallic
hydrogen is primarily a molecular fluid. (Observation of this molecular
metallic state in our experiments was unexpected. Only the monatomic metallic
state was predicted by theory.) In looking at the insulator-to-metal
transition, we focused on the changes in electronic energy band-gap (measured
in electron volts) in hydrogen under shock compression. The value of the
electronic band-gap is the energy that must be absorbed by an electron in
order for it to contribute to electrical conduction. A zero band-gap is
characteristic of a metal; a positive, nonzero band-gap is characteristic
of an insulator. Thus, the magnitude of the band-gap of an insulator is
a measure of how far away the insulator is from being a metal. At ambient pressure, condensed
molecular hydrogen has a wide band-gap (about 15 electron volts), making
it a transparent insulator, like glass. Theory said that when hydrogen is
squeezed by tremendous pressure, the gap would close to zero (the band-gap
of metals, which are nontransparent conductors). Our studies show that when
shocked multiple times in a very cold liquid state, hydrogen becomes first
a semiconductor and then a fluid metal when, as its density increases, its
temperature becomes equal to the band-gap at about 0.3 electron volts (Figure
3). At this point, all the electrons that can be excited by the shock to
conduct electricity have been excited. Insensitive to further decreases
in band-gap, the conductivity stops changing. Our conductivity data for
hydrogen are essentially the same as those for the liquid metals cesium
and rubidium at 2,000 K undergoing the same transition from a semiconducting
to metallic fluid. The comparison is shown in Figure 4.
|


Implications/Future Research Our gas-gun experiments enhance
collective knowledge about the interiors of giant planets. Our earlier studies
of temperature measurements of shock-compressed liquid hydrogen led us to
conclude that Jupiter's molecular envelope is cooler and has much less temperature
variation than previously believed. Further interpretation of those data
suGasGunests that there may be no distinct boundary between Jupiter's core
and mantle, as there is on Earth.6 Jupiter, which is almost 90% hydrogen,
is not the only planet rich in metallic hydrogen. Hot metallic hydrogen
is believed to make up the interior of Saturn and may be present in other
large planets discovered recently outside our solar system. The presence
of metallic hydrogen in these planets has a pronounced effect on their behavior.
On Jupiter, given its extreme internal pressures, the bulk of hydrogen is
most likely in the fluid metallic state; in fact, given the pressure at
which hydrogen metallizes, much more metallic hydrogen--the equivalent of
50 times the mass of Earth--exists in Jupiter than previously believed.
We also assume this metallic hydrogen is the source of Jupiter's very strong
magnetic field, the largest of any planet in our solar system. The results of our experiments
lend credence to the theory that Jupiter's magnetic field is produced not
in the core, but close to the Jovian surface (Figure 5). Based on our data,
it appears that the band of conductivity producing the magnetic field is
much closer to the planet's surface than was thought to be the case.7 We anticipate that laser fusion
scientists, who use the compressibility of hydrogen to tune laser pulses,
also will find the results of our metallic hydrogen experiments extremely
useful. Our experiments provide new insight into the behavior of deuterium
and tritium, isotopic forms of hydrogen used in laser fusion targets. Higher
fusion-energy yields could result from an improved understanding of the
temperature-pressure relationship in hydrogen and its isotopes. Indeed,
our hydrogen metallization studies suGasGunest strongly that the revised
computation of the equation of state of hydrogen at intense pressures will
help in perfecting the hydrogen-isotope-filled targets being designed for
the National Ignition Facility, making their performance range broader and
more flexible. This is also encouraging news for the science-based stockpile
stewardship research that will eventually be performed on NIF. Future experiments will focus on
(1) using various hydrogen isotopes--molecular hydrogen, deuterium, and
hydrogen-deuterium--to determine the temperature dependence of the electronic
energy gap, (2) exploring higher pressures up to 3 Mbar, and (3) probing
effects in similar liquids such as molecular nitrogen and argon.
|
|
Scientific and Technological Applications
|
Key Words: gas gun; hydrogen--fluid, liquid, metallic; Jupiter; National Ignition Facility; shock compression tests; stockpile stewardship.
References
1. S. T. Weir, A. C. Mitchell, and W. J. Nellis, "Metallization of Fluid Molecular Hydrogen," Physical Review Letters 76, 1860 (1996).
2. R. S. Hawke, et al., "Observation of Electrical Conductivity of Isentropically Compressed Hydrogen at Mbar Pressures," Physical Review Letters 41, 994 (1978).
3. "The Diamond Anvil Cell: Probing the Behavior of Metals under Ultrahigh Pressures," Science & Technology Review, UCRL-52000-3-96 (March 1996), pp. 17-27.
4. R. J. Hemley, et al., "Synchrontron Infrared Spectroscopy to 0.15 eV of H2 and D2 at Megabar Pressures," Physical Review Letters 76, 1667 (1996) and H. N. Chen, et al., "Extended Infrared Studies of High Pressure Hydrogen," Physical Review Letters 76, 1663 (1996).
5. W. J. Nellis, et al., "Electronic Energy Gap of Molecular Hydrogen from Electrical Conductivity Measurements at High Shock Pressures," Physical Review Letters 68, 2937 (1992).
6. W. J. Nellis, M. Ross, and N. C. Holmes, "Temperature Measurements of Shock-Compressed Liquid Hydrogen: Implications for the Interior of Jupiter," Science 269, 1249 (1995).
7. W. J. Nellis, S. T. Weir, and A. C. Mitchell, "Metallization and Electrical Conductivity of Hydrogen in Jupiter," Science (in press).
Physicist WILLIAM NELLIS joined the
Laboratory in 1973. His specialty is the investigation of condensed matter both
during and after high-pressure shock compression. The highlight of this work
is the observation of the metallization of fluid hydrogen at 1.4 megabars pressure
and nine-fold compression. He has delivered invited talks at 44 professional
conferences since 1979 and is the author or co-author of more than 100 papers.
A fellow of the American Physical Society's Division of Condensed Matter Physics,
Nellis holds M.S. and Ph.D. degrees in physics from Iowa State University. He
received his B.S. in physics from Loyola University of Chicago.